Electrochemistry in liquid sulfur dioxide. 4. Electrochemical production of highly oxidized forms of ferrocene, decamethylferrocene and iron bis(tris(1-pyrazolyl)borate)
نویسندگان
چکیده
Inorganic Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electrochemistry in liquid sulfur dioxide. 4. Electrochemical production of highly oxidized forms of ferrocene, decamethylferrocene and iron bis(tris(1-pyrazolyl)borate) Paul R. Sharp, and Allen J. Bard Inorg. Chem., 1983, 22 (19), 2689-2693• DOI: 10.1021/ic00161a010 • Publication Date (Web): 01 May 2002 Downloaded from http://pubs.acs.org on February 12, 2009
منابع مشابه
Electrochemistry in liquid sulfur dioxide. 3. Electrochemical production of new highly oxidized 2,2'-bipyridine complexes of ruthenium and iron
The electrochemical oxidation of R ~ ( b p y ) ~ ~ + and Fe(bpy)32+ in liquid sulfur dioxide was investigated. Ru(bpy),2+ shows two oxidation waves corresponding to the 3+ (1.01 V) and 4+ (2.76 V) forms while Fe(bpy),*+ undergoes three oxidations to the 3+ (0 .70 V), 4+ (2.92 V), and 5+ ( -3 .09 V) forms. While the 3+ form is stable. for both compounds on a coulometric time scale, the higher ox...
متن کاملElectrochemistry in liquid sulfur dioxide. 12. Electrochemical and pulse radiolysis studies on oxidation of tris(2,2'-bipyridine)zinc(2+), tris(2,2'-bipyridine)cadmium(2+) and 2,2'-bipyridine
Inorganic Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electrochemistry in liquid sulfur dioxide. 12. Electrochemical and pulse radiolysis studies on oxidation of tris(2,2'-bipyridine)zinc(2+), tris(2,2'-bipyridine)cadmium(2+) and 2,2'-bipyridine Jerzy B. Chlistunoff, and Allen J. Bard Inorg. Chem., 1993, 32 (16), 3521-3527 • DOI: 10....
متن کاملThe elusive tripodal tris(2-pyridyl)borate ligand: a strongly coordinating tetraarylborate.
Tris(2-pyridyl)borates are introduced as a new robust and tunable "scorpionate"-type ligand family. A facile synthesis of this hitherto unknown ligand and its complexation to Fe(II) are described; the optical and electrochemical properties of the resulting iron complex are compared to complexes derived from tris(pyrazolyl)borate, tris(2-pyridyl)aluminate, and corresponding charge-neutral ligands.
متن کاملElectrochemistry in liquid sulfur dioxide. 6. Electrochemical production and isolation of tetrakis(pyridine N-oxide)copper(III) hexafluorophosphate
Inorganic Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electrochemistry in liquid sulfur dioxide. 6. Electrochemical production and isolation of tetrakis(pyridine N-oxide)copper(III) hexafluorophosphate Paul R. Sharp, and Allen J. Bard Inorg. Chem., 1983, 22 (23), 3462-3464• DOI: 10.1021/ic00165a019 • Publication Date (Web): 01 May 20...
متن کاملScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core.
A new tris(pyrazolyl)borate ligand bearing phosphine donor groups appended to the 3-position of the pyrazolyl rings is reported, and the hemilabile behaviour of this tris-N,P ligand in coordination with K+, Tl+ and Cu+ ions is investigated.
متن کامل